Interesting Tutorials

Basic Defending

or try this: http://kitanamedia.com/forums/viewtopic.php?f=9&t=5192

Free Kicks

Penalties

Shoots/Long shoots:
http://www.konami-pes2012.com/eu/en/2011/12/pes-2012-tip-the-controlled-shot/ 
http://www.konami-pes2012.com/eu/en/2011/12/pes-2012-tip-shot-power-as-an-influencing-factor/
http://www.konami-pes2012.com/eu/en/2012/01/pes-2012-tip-long-shots/

Advanced Run Around Tutorial